| 3641516 | WRITE ONCE READ ONLY STORE SEMICONDUCTOR MEMORY | February, 1972 | Casruccci et al. | |
| 3665423 | MEMORY MATRIX USING MIS SEMICONDUCTOR ELEMENT | May, 1972 | Nakamuma et al. | |
| 3877054 | Semiconductor memory apparatus with a multilayer insulator contacting the semiconductor | April, 1975 | Boulin et al. | |
| 3964085 | Method for fabricating multilayer insulator-semiconductor memory apparatus | June, 1976 | Kahng et al. | |
| 3978577 | Fixed and variable threshold N-channel MNOSFET integration technique | September, 1976 | Bhattacharyya et al. | |
| 4152627 | Low power write-once, read-only memory array | May, 1979 | Priel et al. | |
| 4173791 | Insulated gate field-effect transistor read-only memory array | November, 1979 | Bell | |
| 4217601 | Non-volatile memory devices fabricated from graded or stepped energy band gap insulator MIM or MIS structure | August, 1980 | DeKeersmaecker et al. | |
| 4295150 | Storage transistor | October, 1981 | Adam | |
| 4412902 | Method of fabrication of Josephson tunnel junction | November, 1983 | Michikami et al. | |
| 4449205 | Dynamic RAM with non-volatile back-up storage and method of operation thereof | May, 1984 | Hoffman | |
| 4495219 | Process for producing dielectric layers for semiconductor devices | January, 1985 | Kato et al. | |
| 4507673 | Semiconductor memory device | March, 1985 | Aoyama et al. | |
| 4661833 | Electrically erasable and programmable read only memory | April, 1987 | Mizutani | |
| 4717943 | Charge storage structure for nonvolatile memories | January, 1988 | Wolf et al. | |
| 4757360 | Floating gate memory device with facing asperities on floating and control gates | July, 1988 | Faraone et al. | |
| 4780424 | Process for fabricating electrically alterable floating gate memory devices | October, 1988 | Holler | |
| 4794565 | Electrically programmable memory device employing source side injection | December, 1988 | Wu et al. | |
| 4829482 | Current metering apparatus for optimally inducing field emission of electrons in tunneling devices and the like | May, 1989 | Owen | |
| 4870470 | Non-volatile memory cell having Si rich silicon nitride charge trapping layer | September, 1989 | Bass, Jr. et al. | |
| 4888733 | Non-volatile memory cell and sensing method | December, 1989 | Mobley | |
| 4939559 | Dual electron injector structures using a conductive oxide between injectors | July, 1990 | DiMaria et al. | |
| 5016215 | High speed EPROM with reverse polarity voltages applied to source and drain regions during reading and writing | May, 1991 | Tigelaar | |
| 5017977 | Dual EPROM cells on trench walls with virtual ground buried bit lines | May, 1991 | Richardson | 257/316 |
| 5021999 | Non-volatile semiconductor memory device with facility of storing tri-level data | June, 1991 | Kohda et al. | |
| 5027171 | Dual polarity floating gate MOS analog memory device | June, 1991 | Reedy et al. | |
| 5042011 | Sense amplifier pulldown device with tailored edge input | August, 1991 | Casper et al. | |
| 5043946 | Semiconductor memory device | August, 1991 | Yamauchi et al. | |
| 5071782 | Vertical memory cell array and method of fabrication | December, 1991 | Mori | |
| 5073519 | Method of fabricating a vertical FET device with low gate to drain overlap capacitance | December, 1991 | Rodder | |
| 5111430 | Non-volatile memory with hot carriers transmitted to floating gate through control gate | May, 1992 | Morie | |
| 5253196 | MOS analog memory with injection capacitors | October, 1993 | Shimabukuro | |
| 5274249 | Superconducting field effect devices with thin channel layer | December, 1993 | Xi et al. | |
| 5280205 | Fast sense amplifier | January, 1994 | Green et al. | |
| 5293560 | Multi-state flash EEPROM system using incremental programing and erasing methods | March, 1994 | Harari | |
| 5298447 | Method of fabricating a flash memory cell | March, 1994 | Hong | |
| 5317535 | Gate/source disturb protection for sixteen-bit flash EEPROM memory arrays | May, 1994 | Talreja et al. | |
| 5332915 | Semiconductor memory apparatus | July, 1994 | Shimoji et al. | |
| 5350738 | Method of manufacturing an oxide superconductor film | September, 1994 | Hase et al. | |
| 5388069 | Nonvolatile semiconductor memory device for preventing erroneous operation caused by over-erase phenomenon | February, 1995 | Kokubo | |
| 5399516 | Method of making shadow RAM cell having a shallow trench EEPROM | March, 1995 | Bergendahl et al. | |
| 5409859 | Method of forming platinum ohmic contact to p-type silicon carbide | April, 1995 | Glass et al. | |
| 5410504 | Memory based on arrays of capacitors | April, 1995 | Ward | |
| 5418389 | Field-effect transistor with perovskite oxide channel | May, 1995 | Watanabe | |
| 5424993 | Programming method for the selective healing of over-erased cells on a flash erasable programmable read-only memory device | June, 1995 | Lee et al. | |
| 5430670 | Differential analog memory cell and method for adjusting same | July, 1995 | Rosenthal | |
| 5434815 | Stress reduction for non-volatile memory cell | July, 1995 | Smarandoiu et al. | |
| 5438544 | Non-volatile semiconductor memory device with function of bringing memory cell transistors to overerased state, and method of writing data in the device | August, 1995 | Makino | |
| 5445984 | Method of making a split gate flash memory cell | August, 1995 | Hong et al. | |
| 5449941 | Semiconductor memory device | September, 1995 | Yamazaki et al. | |
| 5455792 | Flash EEPROM devices employing mid channel injection | October, 1995 | Yi | |
| 5457649 | Semiconductor memory device and write-once, read-only semiconductor memory array using amorphous-silicon and method therefor | October, 1995 | Eichman et al. | |
| 5467306 | Method of using source bias to increase threshold voltages and/or to correct for over-erasure of flash eproms | November, 1995 | Kaya et al. | |
| 5477485 | Method for programming a single EPROM or FLASH memory cell to store multiple levels of data that utilizes a floating substrate | December, 1995 | Bergemont et al. | |
| 5485422 | Drain bias multiplexing for multiple bit flash cell | January, 1996 | Bauer et al. | |
| 5493140 | Nonvolatile memory cell and method of producing the same | February, 1996 | Iguchi | |
| 5497494 | Method for saving and restoring the state of a CPU executing code in protected mode | March, 1996 | Combs et al. | |
| 5498558 | Integrated circuit structure having floating electrode with discontinuous phase of metal silicide formed on a surface thereof and process for making same | March, 1996 | Kapoor | |
| 5508543 | Low voltage memory | April, 1996 | Hartstein et al. | |
| 5508544 | Three dimensional FAMOS memory devices | April, 1996 | Shah | |
| 5510278 | Method for forming a thin film transistor | April, 1996 | Nguyen et al. | |
| 5530581 | Protective overlayer material and electro-optical coating using same | June, 1996 | Cogan | |
| 5530668 | Ferroelectric memory sensing scheme using bit lines precharged to a logic one voltage | June, 1996 | Chern et al. | |
| 5539279 | Ferroelectric memory | July, 1996 | Takeuchi et al. | |
| 5541871 | Nonvolatile ferroelectric-semiconductor memory | July, 1996 | Nishimura et al. | |
| 5541872 | Folded bit line ferroelectric memory device | July, 1996 | Lowrey et al. | |
| 5550770 | Semiconductor memory device having ferroelectric capacitor memory cells with reading, writing and forced refreshing functions and a method of operating the same | August, 1996 | Kuroda | |
| 5557569 | Low voltage flash EEPROM C-cell using fowler-nordheim tunneling | September, 1996 | Smayling et al. | |
| 5572459 | Voltage reference for a ferroelectric 1T/1C based memory | November, 1996 | Wilson et al. | |
| 5600587 | Ferroelectric random-access memory | February, 1997 | Koike | |
| 5600592 | Nonvolatile semiconductor memory device having a word line to which a negative voltage is applied | February, 1997 | Atsumi et al. | |
| 5617351 | Three-dimensional direct-write EEPROM arrays and fabrication methods | April, 1997 | Bertin et al. | |
| 5618575 | Process and apparatus for the production of a metal oxide layer | April, 1997 | Peter | |
| 5619642 | Fault tolerant memory system which utilizes data from a shadow memory device upon the detection of erroneous data in a main memory device | April, 1997 | Nielson et al. | |
| 5621683 | Semiconductor memory with non-volatile memory transistor | April, 1997 | Young | |
| 5627781 | Nonvolatile semiconductor memory | May, 1997 | Hayashi et al. | |
| 5627785 | Memory device with a sense amplifier | May, 1997 | Gilliam et al. | |
| 5646430 | Non-volatile memory cell having lightly-doped source region | July, 1997 | Kaya et al. | |
| 5670790 | Electronic device | September, 1997 | Katoh et al. | |
| 5677867 | Memory with isolatable expandable bit lines | October, 1997 | Hazani | |
| 5691230 | Technique for producing small islands of silicon on insulator | November, 1997 | Forbes | |
| 5714766 | Nano-structure memory device | February, 1998 | Chen et al. | |
| 5740104 | Multi-state flash memory cell and method for programming single electron differences | April, 1998 | Forbes | |
| 5754477 | Differential flash memory cell and method for programming | May, 1998 | Forbes | |
| 5768192 | Non-volatile semiconductor memory cell utilizing asymmetrical charge trapping | June, 1998 | Eitan | |
| 5801401 | Flash memory with microcrystalline silicon carbide film floating gate | September, 1998 | Forbes | |
| 5801993 | Nonvolatile memory device | September, 1998 | Choi | |
| 5828605 | Snapback reduces the electron and hole trapping in the tunneling oxide of flash EEPROM | October, 1998 | Peng et al. | |
| 5852306 | Flash memory with nanocrystalline silicon film floating gate | December, 1998 | Forbes | |
| 5856688 | Integrated circuit memory devices having nonvolatile single transistor unit cells therein | January, 1999 | Lee et al. | |
| 5856943 | Scalable flash EEPROM memory cell and array | January, 1999 | Jeng | |
| 5880991 | Structure for low cost mixed memory integration, new NVRAM structure, and process for forming the mixed memory and NVRAM structure | March, 1999 | Hsu et al. | |
| 5886368 | Transistor with silicon oxycarbide gate and methods of fabrication and use | March, 1999 | Forbes et al. | |
| 5912488 | Stacked-gate flash EEPROM memory devices having mid-channel injection characteristics for high speed programming | June, 1999 | Kim et al. | |
| 5923056 | Electronic components with doped metal oxide dielectric materials and a process for making electronic components with doped metal oxide dielectric materials | July, 1999 | Lee et al. | |
| 5936274 | High density flash memory | August, 1999 | Forbes et al. | |
| 5943262 | Non-volatile memory device and method for operating and fabricating the same | August, 1999 | Choi | |
| 5952692 | Memory device with improved charge storage barrier structure | September, 1999 | Nakazato et al. | |
| 5959896 | Multi-state flash memory cell and method for programming single electron differences | September, 1999 | Forbes | |
| 5963476 | Fowler-Nordheim (F-N) tunneling for pre-programming in a floating gate memory device | October, 1999 | Hung et al. | |
| 5973356 | Ultra high density flash memory | October, 1999 | Noble et al. | |
| 5981335 | Method of making stacked gate memory cell structure | November, 1999 | Chi | |
| 5981350 | Method for forming high capacitance memory cells | November, 1999 | Geusic et al. | |
| 5986932 | Non-volatile static random access memory and methods for using same | November, 1999 | Ratnakumar et al. | |
| 5989958 | Flash memory with microcrystalline silicon carbide film floating gate | November, 1999 | Forbes | |
| 5991225 | Programmable memory address decode array with vertical transistors | November, 1999 | Forbes et al. | |
| 6011725 | Two bit non-volatile electrically erasable and programmable semiconductor memory cell utilizing asymmetrical charge trapping | January, 2000 | Eitan | |
| 6025228 | Method of fabricating an oxynitride-capped high dielectric constant interpolysilicon dielectric structure for a low voltage non-volatile memory | February, 2000 | Ibok et al. | |
| 6025627 | Alternate method and structure for improved floating gate tunneling devices | February, 2000 | Forbes et al. | |
| 6031263 | DEAPROM and transistor with gallium nitride or gallium aluminum nitride gate | February, 2000 | Forbes et al. | |
| 6034882 | Vertically stacked field programmable nonvolatile memory and method of fabrication | March, 2000 | Johnson et al. | |
| 6049479 | Operational approach for the suppression of bi-directional tunnel oxide stress of a flash cell | April, 2000 | Thurgate et al. | |
| 6069380 | Single-electron floating-gate MOS memory | May, 2000 | Chou et al. | |
| 6069816 | High-speed responding data storing device for maintaining stored data without power supply | May, 2000 | Nishimura | |
| 6072209 | Four F.sup.2 folded bit line DRAM cell structure having buried bit and word lines | June, 2000 | Noble et al. | |
| 6101131 | Flash EEPROM device employing polysilicon sidewall spacer as an erase gate | August, 2000 | Chang | |
| 6111788 | Method for programming and erasing a triple-poly split-gate flash | August, 2000 | Chen et al. | |
| 6115281 | Methods and structures to cure the effects of hydrogen annealing on ferroelectric capacitors | September, 2000 | Aggarwal et al. | |
| 6122201 | Clipped sine wave channel erase method to reduce oxide trapping charge generation rate of flash EEPROM | September, 2000 | Lee et al. | |
| 6124729 | Field programmable logic arrays with vertical transistors | September, 2000 | Noble et al. | |
| 6125062 | Single electron MOSFET memory device and method | September, 2000 | Ahn et al. | |
| 6127227 | Thin ONO thickness control and gradual gate oxidation suppression by b. N.su2 treatment in flash memory | October, 2000 | Lin et al. | |
| 6134175 | Memory address decode array with vertical transistors | October, 2000 | Forbes et al. | |
| 6140181 | Memory using insulator traps | October, 2000 | Forbes et al. | |
| 6141237 | Ferroelectric non-volatile latch circuits | October, 2000 | Eliason et al. | |
| 6141238 | Dynamic random access memory (DRAM) cells with repressed ferroelectric memory methods of reading same, and apparatuses including same | October, 2000 | Forbes et al. | |
| 6141248 | DRAM and SRAM memory cells with repressed memory | October, 2000 | Forbes et al. | |
| 6141260 | Single electron resistor memory device and method for use thereof | October, 2000 | Ahn et al. | |
| 6143636 | High density flash memory | November, 2000 | Forbes et al. | |
| 6150687 | Memory cell having a vertical transistor with buried source/drain and dual gates | November, 2000 | Noble et al. | |
| 6153468 | Method of forming a logic array for a decoder | November, 2000 | Forbes et al. | |
| 6163049 | Method of forming a composite interpoly gate dielectric | December, 2000 | Bui | |
| 6166401 | Flash memory with microcrystalline silicon carbide film floating gate | December, 2000 | Forbes | |
| 6169306 | Semiconductor devices comprised of one or more epitaxial layers | January, 2001 | Gardner et al. | |
| 6185122 | Vertically stacked field programmable nonvolatile memory and method of fabrication | February, 2001 | Johnson et al. | |
| 6201734 | Programmable impedance device | March, 2001 | Sansbury et al. | |
| 6208164 | Programmable logic array with vertical transistors | March, 2001 | Noble et al. | |
| 6210999 | Method and test structure for low-temperature integration of high dielectric constant gate dielectrics into self-aligned semiconductor devices | April, 2001 | Gardner et al. | |
| 6212103 | Method for operating flash memory | April, 2001 | Ahrens et al. | |
| 6229175 | Nonvolatile memory | May, 2001 | Uchida | |
| 6232643 | Memory using insulator traps | May, 2001 | Forbes et al. | |
| 6238976 | Method for forming high density flash memory | May, 2001 | Noble et al. | |
| 6243300 | Substrate hole injection for neutralizing spillover charge generated during programming of a non-volatile memory cell | June, 2001 | Sunkavalli | |
| 6246606 | Memory using insulator traps | June, 2001 | Forbes et al. | |
| 6249020 | DEAPROM and transistor with gallium nitride or gallium aluminum nitride gate | June, 2001 | Forbes et al. | |
| 6249460 | Dynamic flash memory cells with ultrathin tunnel oxides | June, 2001 | Forbes et al. | |
| 6252793 | Reference cell configuration for a 1T/1C ferroelectric memory | June, 2001 | Allen et al. | |
| 6255683 | Dynamic random access memory | July, 2001 | Radens et al. | |
| 6269023 | Method of programming a non-volatile memory cell using a current limiter | July, 2001 | Derhacobian et al. | |
| 6288419 | Low resistance gate flash memory | September, 2001 | Prall et al. | |
| 6294813 | Information handling system having improved floating gate tunneling devices | September, 2001 | Forbes et al. | |
| 6307775 | Deaprom and transistor with gallium nitride or gallium aluminum nitride gate | October, 2001 | Forbes et al. | |
| 6310376 | Semiconductor storage device capable of improving controllability of density and size of floating gate | October, 2001 | Ueda et al. | |
| 6323844 | Cursor controlling device and the method of the same | November, 2001 | Yeh et al. | |
| 6337805 | Discrete devices including EAPROM transistor and NVRAM memory cell with edge defined ferroelectric capacitance, methods for operating same, and apparatuses including same | January, 2002 | Forbes et al. | |
| 6351411 | Memory using insulator traps | February, 2002 | Forbes et al. | |
| 6365470 | Method for manufacturing self-matching transistor | April, 2002 | Maeda | |
| 6407435 | Multilayer dielectric stack and method | June, 2002 | Ma et al. | |
| 6424001 | Flash memory with ultra thin vertical body transistors | July, 2002 | Forbes et al. | |
| 6438031 | Method of programming a non-volatile memory cell using a substrate bias | August, 2002 | Fastow | |
| 6444545 | Device structure for storing charge and method therefore | September, 2002 | Sadd et al. | |
| 6445030 | Flash memory erase speed by fluorine implant or fluorination | September, 2002 | Wu et al. | |
| 6449188 | Low column leakage nor flash array-double cell implementation | September, 2002 | Fastow | |
| 6456531 | Method of drain avalanche programming of a non-volatile memory cell | September, 2002 | Wang et al. | |
| 6456536 | Method of programming a non-volatile memory cell using a substrate bias | September, 2002 | Sobek et al. | |
| 6459618 | Method of programming a non-volatile memory cell using a drain bias | October, 2002 | Wang | |
| 6461931 | Thin dielectric films for DRAM storage capacitors | October, 2002 | Eldridge | |
| 6475857 | Method of making a scalable two transistor memory device | November, 2002 | Kim et al. | |
| 6487121 | Method of programming a non-volatile memory cell using a vertical electric field | November, 2002 | Thurgate et al. | |
| 6490205 | Method of erasing a non-volatile memory cell using a substrate bias | December, 2002 | Wang et al. | |
| 6495436 | Formation of metal oxide gate dielectric | December, 2002 | Ahn et al. | |
| 6498362 | Weak ferroelectric transistor | December, 2002 | Forbes et al. | |
| 6504755 | Semiconductor memory device | January, 2003 | Katayama et al. | |
| 6514828 | Method of fabricating a highly reliable gate oxide | February, 2003 | Ahn et al. | |
| 6521950 | Ultra-high resolution liquid crystal display on silicon-on-sapphire | February, 2003 | Shimabukuro et al. | |
| 6521958 | MOSFET technology for programmable address decode and correction | February, 2003 | Forbes et al. | |
| 6534420 | Methods for forming dielectric materials and methods for forming semiconductor devices | March, 2003 | Ahn et al. | |
| 6541280 | High K dielectric film | April, 2003 | Kaushik et al. | |
| 6541816 | Planar structure for non-volatile memory devices | April, 2003 | Ramsbey et al. | |
| 6545314 | Memory using insulator traps | April, 2003 | Forbes et al. | |
| 6552387 | Non-volatile electrically erasable and programmable semiconductor memory cell utilizing asymmetrical charge trapping | April, 2003 | Eitan | |
| 6559014 | Preparation of composite high-K / standard-K dielectrics for semiconductor devices | May, 2003 | Jeon | |
| 6566699 | Non-volatile electrically erasable and programmable semiconductor memory cell utilizing asymmetrical charge trapping | May, 2003 | Eitan | |
| 6567303 | Charge injection | May, 2003 | Hamilton et al. | |
| 6567312 | Non-volatile semiconductor memory device having a charge storing insulation film and data holding method therefor | May, 2003 | Torii et al. | |
| 6570787 | Programming with floating source for low power, low leakage and high density flash memory devices | May, 2003 | Wang et al. | |
| 6580124 | Multigate semiconductor device with vertical channel current and method of fabrication | June, 2003 | Cleeves et al. | |
| 6586785 | Aerosol silicon nanoparticles for use in semiconductor device fabrication | July, 2003 | Flagan et al. | |
| 6586797 | Graded composition gate insulators to reduce tunneling barriers in flash memory devices | July, 2003 | Forbes et al. | |
| 6600188 | EEPROM with a neutralized doping at tunnel window edge | July, 2003 | Jiang et al. | |
| 6618290 | Method of programming a non-volatile memory cell using a baking process | September, 2003 | Wang et al. | |
| 6630381 | Preventing dielectric thickening over a floating gate area of a transistor | October, 2003 | Hazani | |
| 6642573 | Use of high-K dielectric material in modified ONO structure for semiconductor devices | November, 2003 | Halliyal et al. | |
| 6674138 | Use of high-k dielectric materials in modified ONO structure for semiconductor devices | January, 2004 | Halliyal et al. | |
| 6867097 | Method of making a memory cell with polished insulator layer | March, 2005 | Ramsbey et al. | |
| 6996009 | NOR flash memory cell with high storage density | February, 2006 | Forbes | |
| 7045430 | Atomic layer-deposited LaAlO3 films for gate dielectrics | May, 2006 | Ahn et al. | |
| 7193893 | Write once read only memory employing floating gates | March, 2007 | Forbes | |
| 7221017 | Memory utilizing oxide-conductor nanolaminates | May, 2007 | Forbes et al. | |
| 7221586 | Memory utilizing oxide nanolaminates | May, 2007 | Forbes et al. | |
| 20010013621 | Memory Device | August, 2001 | Nakazato | |
| 20020003252 | FLASH MEMORY CIRCUIT WITH WITH RESISTANCE TO DISTURB EFFECT | January, 2002 | Iyer | |
| 20020027264 | MOSFET technology for programmable address decode and correction | March, 2002 | Forbes et al. | |
| 20020036939 | Qualfication test method and circuit for a non-volatile memory | March, 2002 | Tsai et al. | |
| 20020074565 | Aerosol silicon nanoparticles for use in semiconductor device fabrication | June, 2002 | Flagan et al. | |
| 20020106536 | Dielectric layer for semiconductor device and method of manufacturing the same | August, 2002 | Lee et al. | |
| 20020109158 | Dynamic memory based on single electron storage | August, 2002 | Forbes et al. | |
| 20020115252 | Dielectric interface films and methods therefor | August, 2002 | Haukka et al. | |
| 20020137250 | High K dielectric film and method for making | September, 2002 | Nguyen et al. | |
| 20020192974 | Dielectric layer forming method and devices formed therewith | December, 2002 | Ahn et al. | |
| 20030017717 | METHODS FOR FORMING DIELECTRIC MATERIALS AND METHODS FOR FORMING SEMICONDUCTOR DEVICES | January, 2003 | Ahn et al. | |
| 20030032270 | Fabrication method for a device for regulating flow of electric current with high dielectric constant gate insulating layer and source/drain forming schottky contact or schottky-like region with substrate | February, 2003 | Snyder et al. | |
| 20030042527 | Programmable array logic or memory devices with asymmetrical tunnel barriers | March, 2003 | Forbes et al. | |
| 20030042532 | In service programmable logic arrays with low tunnel barrier interpoly insulators | March, 2003 | Forbes | |
| 20030043622 | DRAM Cells with repressed floating gate memory, low tunnel barrier interpoly insulators | March, 2003 | Forbes | |
| 20030043630 | DEAPROM WITH INSULATING METAL OXIDE INTERPOLY INSULATORS | March, 2003 | Forbes et al. | |
| 20030043632 | Programmable memory address and decode circuits with low tunnel barrier interpoly insulators | March, 2003 | Forbes | |
| 20030043633 | Programmable array logic or memory with p-channel devices and asymmetrical tunnel barriers | March, 2003 | Forbes et al. | |
| 20030043637 | Flash memory with low tunnel barrier interpoly insulators | March, 2003 | Forbes et al. | |
| 20030045082 | Atomic layer deposition of metal oxide and/or low asymmetrical tunnel barrier interploy insulators | March, 2003 | Eldridge et al. | |
| 20030048666 | Graded composition metal oxide tunnel barrier interpoly insulators | March, 2003 | Eldridge et al. | |
| 20030235077 | Write once read only memory employing floating gates | December, 2003 | Forbes | |
| 20030235081 | Nanocrystal write once read only memory for archival storage | December, 2003 | Forbes | |
| 20030235085 | WRITE ONCE READ ONLY MEMORY EMPLOYING CHARGE TRAPPING IN INSULATORS | December, 2003 | Forbes | |
| 20040004245 | Memory utilizing oxide-conductor nanolaminates | January, 2004 | Forbes et al. | |
| 20040004247 | Memory utilizing oxide-nitride nanolaminates | January, 2004 | Forbes et al. | |
| 20040004859 | Memory utilizing oxide nanolaminates | January, 2004 | Forbes et al. | |
| 20040063276 | Process for producing semiconductor integated circuit device | April, 2004 | Yamamoto et al. | |
| 20060001080 | Write once read only memory employing floating gates | January, 2006 | Forbes | |
| 20060002188 | Write once read only memory employing floating gates | January, 2006 | Forbes | |
| 20060008966 | Memory utilizing oxide-conductor nanolaminates | January, 2006 | Forbes et al. | |
| 20070178643 | Memory utilizing oxide-conductor nanolaminates | August, 2007 | Forbes et al. |
| JP61166078 | July, 1986 | FLOATING-GATE TYPE NONVOLATILE MEMORY ELEMENT | ||
| JP03222367 | October, 1991 | INSULATED GATE TYPE FIELD EFFECT TRANSISTOR | ||
| JP06224431 | August, 1994 | THIN-FILM TRANSISTOR AND LIQUID CRYSTAL DISPLAY PANEL | ||
| JP06302828 | October, 1994 | NONVOLATILE SEMICONDUCTOR MEMORY DEVICE | ||
| JP08255878 | October, 1996 | FLOATING GATE TRANSISTOR AND FABRICATION THEREOF | ||
| WO-9907000 | February, 1999 | |||
| WO-9917371 | April, 1999 |
This application is a continuation of U.S. patent application Ser. No. 10/190,717, filed Jul. 8, 2002 and issued on May 22, 2007 as U.S. Pat. No. 7,221,586, which is incorporated herein by reference.
This application is related to the following co-pending, commonly assigned U.S. patent applications: “Memory Utilizing Oxide-Nitride Nanolaminates,” Ser. No. 10/190,689, and “Memory Utilizing Oxide-Conductor Nanolaminates,” U.S. Pat. No. 7,221,017, each of which disclosure is herein incorporated by reference.
The present invention relates generally to semiconductor intergrated circuits and, more particularly, to memory utilizing oxide nanolaminates.
Many electronic products need various amounts of memory to store information, e.g. data. One common type of high speed, low cost memory includes dynamic random access memory (DRAM) comprised of individual DRAM cells arranged in arrays. DRAM cells include an access transistor, e.g a metal oxide semiconducting field effect transistor (MOSFET), coupled to a capacitor cell.
Another type of high speed, low cost memory includes floating gate memory cells. A conventional horizontal floating gate transistor structure includes a source region and a drain region separated by a channel region in a horizontal substrate. A floating gate is separated by a thin tunnel gate oxide. The structure is programmed by storing a charge on the floating gate. A control gate is separated from the floating gate by an intergate dielectric. A charge stored on the floating gate effects the conductivity of the cell when a read voltage potential is applied to the control gate. The state of cell can thus be determined by sensing a change in the device conductivity between the programmed and un-programmed states.
With successive generations of DRAM chips, an emphasis continues to be placed on increasing array density and maximizing chip real estate while minimizing the cost of manufacture. It is further desirable to increase array density with little or no modification of the DRAM optimized process flow.
Multilayer insulators have been previously employed in memory devices. The devices in the above references employed oxide-tungsten oxide-oxide layers. Other previously described structures described have employed charge-trapping layers implanted into graded layer insulator structures.
More recently oxide-nitride-oxide structures have been described for high density nonvolatile memories. All of these are variations on the original MNOS memory structure described by Fairchild Semiconductor in 1969 which was conceptually generalized to include trapping insulators in general for constructing memory arrays.
Studies of charge trapping in MNOS structures have also been conducted by White and others.
Some commercial and military applications utilized non-volatile MNOS memones.
However, these structures did not gain widespread acceptance and use due to their variability in characteristics and unpredictable charge trapping phenomena. They all depended upon the trapping of charge at interface states between the oxide and other insulator layers or poorly characterized charge trapping centers in the insulator layers themselves. Since the layers were deposited by CVD, they are thick, have poorly controlled thickness and large surface state charge-trapping center densities between the layers.
Thus, there is an ongoing need for improved DRAM technology compatible transistor cells. It is desirable that such transistor cells be fabricated on a DRAM chip with little or no modification of the DRAM process flow. It is further desirable that such transistor cells provide increased density and high access and read speeds.
FIG. 1A is a block diagram of a metal oxide semiconductor field effect transistor (MOSFET) in a substrate according to the teachings of the prior art.
FIG. 1B illustrates the MOSFET of FIG. 1A operated in the forward direction showing some degree of device degradation due to electrons being trapped in the gate oxide near the drain region over gradual use.
FIG. 1C is a graph showing the square root of the current signal (Ids) taken at the drain region of the conventional MOSFET versus the voltage potential (VGS) established between the gate and the source region.
FIG. 2A is a diagram of an embodiment for a programmed MOSFET, having oxide insulator nanolaminate layers, which can be used as a transistor cell according to the teachings of the present invention.
FIG. 2B is a diagram suitable for explaining a method embodiment by which a MOSFET, having oxide insulator nanolaminate layers, can be programmed to achieve the embodiments of the present invention.
FIG. 2C is a graph plotting the current signal (Ids) detected at the drain region versus a voltage potential, or drain voltage, (VDS) set up between the drain region and the source region (Ids vs. VDS).
FIG. 3 illustrates a portion of an embodiment of a memory array according to the teachings of the present invention.
FIG. 4 illustrates an electrical equivalent circuit 400 for the portion of the memory array shown in FIG. 3.
FIG. 5 illustrates an energy band diagram for an embodiment of a gate stack according to the teachings of the present invention.
FIG. 6 is a graph which plots electron affinity versus the energy bandgap for various insulators.
FIGS. 7A-7B illustrates an embodiment for the operation of a transistor cell having oxide insulator nanolaminate layers according to the teachings of the present invention.
FIG. 8 illustrates the operation of a conventional DRAM cell.
FIG. 9 illustrates an embodiment of a memory device according to the teachings of the present invention.
FIG. 10 is a schematic diagram illustrating a conventional NOR-NOR programmable logic array.
FIG. 11 is a schematic diagram illustrating generally an architecture of one embodiment of a programmable logic array (PLA) with logic cells, having oxide insulator nanolaminate layers according to the teachings of the present invention.
FIG. 12 is a block diagram of an electrical system, or processor-based system, utilizing oxide nanolaminates constructed in accordance with the present invention.
In the following detailed description of the invention, reference is made to the accompanying drawings which form a part hereof, and in which is shown, by way of illustration, specific embodiments in which the invention may be practiced. In the drawings, like numerals describe substantially similar components throughout the several views. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention. Other embodiments may be utilized and structural, logical, and electrical changes may be made without departing from the scope of the present invention.
The terms wafer and substrate used in the following description include any structure having an exposed surface with which to form the integrated circuit (IC) structure of the invention. The term substrate is understood to include semiconductor wafers. The term substrate is also used to refer to semiconductor structures during processing, and may include other layers that have been fabricated thereupon. Both wafer and substrate include doped and undoped semiconductors, epitaxial semiconductor layers supported by a base semiconductor or insulator, as well as other semiconductor structures well known to one skilled in the art. The term conductor is understood to include semiconductors, and the term insulator is defined to include any material that is less electrically conductive than the materials referred to as conductors. The following detailed description is, therefore, not to be taken in a limiting sense, and the scope of the present invention is defined only by the appended claims, along with the full scope of equivalents to which such claims are entitled.
FIG. 1A is useful in illustrating the conventional operation of a MOSFET such as can be used in a DRAM array. FIG. 1A illustrates the normal hot electron injection and degradation of devices operated in the forward direction. As is explained below, since the electrons are trapped near the drain they are not very effective in changing the device characteristics.
FIG. 1A is a block diagram of a metal oxide semiconductor field effect transistor (MOSFET) 101 in a substrate 100 . The MOSFET 101 includes a source region 102 , a drain region 104 , a channel region 106 in the substrate 100 between the source region 102 and the drain region 104 . A gate 108 is separated from the channel region 108 by a gate oxide 110 . A sourceline 112 is coupled to the source region 102 . A bitline 114 is coupled to the drain region 104 . A wordline 116 is coupled to the gate 108 .
In conventional operation, a drain to source voltage potential (Vds) is set up between the drain region 104 and the source region 102 . A voltage potential is then applied to the gate 108 via a wordline 116 . Once the voltage potential applied to the gate 108 surpasses the characteristic voltage threshold (Vt) of the MOSFET a channel 106 forms in the substrate 100 between the drain region 104 and the source region 102 . Formation of the channel 106 permits conduction between the drain region 104 and the source region 102 , and a current signal (Ids) can be detected at the drain region 104 .
In operation of the conventional MOSFET of FIG. 1A, some degree of device degradation does gradually occur for MOSFETs operated in the forward direction by electrons 117 becoming trapped in the gate oxide 110 near the drain region 104 . This effect is illustrated in FIG. 1B. However, since the electrons 117 are trapped near the drain region 104 they are not very effective in changing the MOSFET characteristics.
FIG. 1C illustrates this point. FIG. 1C is a graph showing the square root of the current signal (Ids) taken at the drain region versus the voltage potential (VGS) established between the gate 108 and the source region 102 . The change in the slope of the plot of SQRT Ids versus VGS represents the change in the charge carrier mobility in the channel 106 .
In FIG. 1C, ΔVT represents the minimal change in the MOSFET's threshold voltage resulting from electrons gradually being trapped in the gate oxide 110 near the drain region 104 , under normal operation, due to device degradation. This results in a fixed trapped charge in the gate oxide 110 near the drain region 104 . Slope 103 represents the charge carrier mobility in the channel 106 for FIG. 1A having no electrons trapped in the gate oxide 110 . Slope 105 represents the charge mobility in the channel 106 for the conventional MOSFET of FIG. 1B having electrons 117 trapped in the gate oxide 110 near the drain region 104 . As shown by a comparison of slope 103 and slope 105 in FIG. 1C, the electrons 117 trapped in the gate oxide 110 near the drain region 104 of the conventional MOSFET do not significantly change the charge mobility in the channel 106 .
There are two components to the effects of stress and hot electron injection. One component includes a threshold voltage shift due to the trapped electrons and a second component includes mobility degradation due to additional scattering of carrier electrons caused by this trapped charge and additional surface states. When a conventional MOSFET degrades, or is “stressed,” over operation in the forward direction, electrons do gradually get injected and become trapped in the gate oxide near the drain. In this portion of the conventional MOSFET there is virtually no channel underneath the gate oxide. Thus the trapped charge modulates the threshold voltage and charge mobility only slightly.
One of the inventors, along with others, has previously described programmable memory devices and functions based on the reverse stressing of MOSFET's in a conventional CMOS process and technology in order to form programmable address decode and correction in U.S. Pat. No. 6,521,950 entitled “MOSFET Technology for Programmable Address Decode and Correction.” That disclosure, however, did not describe write once read only memory solutions, but rather address decode and correction issues. One of the inventors also describes write once read only memory cells employing charge trapping in gate insulators for conventional MOSFETs and write once read only memory employing floating gates. The same are described in co-pending, commonly assigned U.S. patent applications, entitled “Write Once Read Only Memory Employing Charge Trapping in Insulators,” Ser. No. 10/177,077, and “Write Once Read Only Memory Employing Floating Gates,” Ser. No. 10/177,083. The present application, however, describes transistor cells having oxide insulator nanolaminate layers and their use in integrated circuit device structures.
According to the teachings of the present invention, normal flash memory type cells can be programmed by operation in the reverse direction and utilizing avalanche hot electron injection to trap electrons in the gate insulator nanolaminate. When the programmed floating gate transistor is subsequently operated in the forward direction the electrons trapped in the gate insulator nanolaminate cause the channel to have a different threshold voltage. The novel programmed flash memory type transistors of the present invention conduct significantly less current than conventional flash cells which have not been programmed. These electrons will remain trapped in the gate insulator nanolaminate unless negative control gate voltages are applied. The electrons will not be removed from the gate insulator nanolaminate when positive or zero control gate voltages are applied. Erasure can be accomplished by applying negative control gate voltages and/or increasing the temperature with negative control gate bias applied to cause the trapped electrons in the gate insulator nanolaminate to be re-emitted back into the silicon channel of the MOSFET.
FIG. 2A is a diagram of an embodiment for a programmed transistor cell 201 having oxide insulator nanolaminate layers according to the teachings of the present invention. As shown in FIG. 2A the transistor cell 201 includes a transistor in a substrate 200 which has a first source/drain region 202 , a second source/drain region 204 , and a channel region 206 between the first and second source/drain regions, 202 and 204 . In one embodiment, the first source/drain region 202 includes a source region 202 for the transistor cell 201 and the second source/drain region 204 includes a drain region 204 for the transistor cell 201 . FIG. 2A further illustrates the transistor cell 201 having oxide insulator nanolaminate layers 208 separated from the channel region 206 by an oxide 210 . An sourceline or array plate 212 is coupled to the first source/drain region 202 and a transmission line 214 is coupled to the second source/drain region 204 . In one embodiment, the transmission line 214 includes a bit line 214 . Further as shown in FIG. 2A, a gate 216 is separated from the oxide insulator nanolaminate layers 208 by another oxide 218 .
As stated above, transistor cell 201 illustrates an embodiment of a programmed transistor. This programmed transistor has a charge 217 trapped in potential wells in the oxide insulator nanolaminate layers 208 formed by the different electron affinities of the insulators 208 , 210 and 218 . In one embodiment, the charge 217 trapped on the floating gate 208 includes a trapped electron charge 217 .
FIG. 2B is a diagram suitable for explaining the method by which the oxide insulator nanolaminate layers 208 of the transistor cell 201 of the present invention can be programmed to achieve the embodiments of the present invention. As shown in FIG. 2B the method includes programming the floating gate transistor. Programming the floating gate transistor includes applying a first voltage potential V 1 to a drain region 204 of the floating gate transistor and a second voltage potential V 2 to the source region 202 .
In one embodiment, applying a first voltage potential V 1 to the drain region 204 of the floating gate transistor includes grounding the drain region 204 of the floating gate transistor as shown in FIG. 2B. In this embodiment, applying a second voltage potential V 2 to the source region 202 includes biasing the array plate 212 to a voltage higher than VDD, as shown in FIG. 2B. A gate potential VGS is applied to the control gate 216 of the transistor. In one embodiment, the gate potential VGS includes a voltage potential which is less than the second voltage potential V 2 , but which is sufficient to establish conduction in the channel 206 of the transistor between the drain region 204 and the source region 202 . As shown in FIG. 2B, applying the first, second and gate potentials (V 1 , V 2 , and VGS respectively) to the transistor creates a hot electron injection into the oxide insulator nanolaminate layers 208 of the transistor adjacent to the source region 202 . In other words, applying the first, second and gate potentials (V 1 , V 2 , and VGS respectively) provides enough energy to the charge carriers, e.g. electrons, being conducted across the channel 206 that, once the charge carriers are near the source region 202 , a number of the charge carriers get excited into the oxide insulator nanolaminate layers 208 adjacent to the source region 202 . Here the charge carriers become trapped in potential wells in the oxide insulator nanolaminate layers 208 formed by the different electron affinities of the insulators 208 , 210 and 218 .
In an alternative embodiment, applying a first voltage potential V 1 to the drain region 204 of the transistor includes biasing the drain region 204 of the transistor to a voltage higher than VDD. In this embodiment, applying a second voltage potential V 2 to the source region 202 includes grounding the sourceline or array plate 212 . A gate potential VGS is applied to the control gate 216 of the transistor. In one embodiment, the gate potential VGS includes a voltage potential which is less than the first voltage potential V 1 , but which is sufficient to establish conduction in the channel 206 of the transistor between the drain region 204 and the source region 202 . Applying the first, second and gate potentials (V 1 , V 2 , and VGS respectively) to the transistor creates a hot electron injection into the oxide insulator nanolaminate layers 208 of the transistor adjacent to the drain region 204 . In other words, applying the first, second and gate potentials (V 1 , V 2 , and VGS respectively) provides enough energy to the charge carriers, e.g. electrons, being conducted across the channel 206 that, once the charge carriers are near the drain region 204 , a number of the charge carriers get excited into the oxide insulator nanolaminate layers 208 adjacent to the drain region 204 . Here the charge carriers become trapped in potential wells in the oxide insulator nanolaminate layers 208 formed by the different electron affinities of the insulators 208 , 210 and 218 , as shown in FIG. 2A.
In one embodiment of the present invention, the method is continued by subsequently operating the transistor in the forward direction in its programmed state during a read operation. Accordingly, the read operation includes grounding the source region 202 and precharging the drain region a fractional voltage of VDD. If the device is addressed by a wordline coupled to the gate, then its conductivity will be determined by the presence or absence of stored charge in the oxide insulator nanolaminate layers 208 . That is, a gate potential can be applied to the gate 216 by a wordline 220 in an effort to form a conduction channel between the source and the drain regions as done with addressing and reading conventional DRAM cells.
However, now in its programmed state, the conduction channel 206 of the transistor will have a higher voltage threshold and will not conduct.
FIG. 2C is a graph plotting a current signal (IDS) detected at the second source/drain region 204 versus a voltage potential, or drain voltage, (VDS) set up between the second source/drain region 204 and the first source/drain region 202 (IDS vs. VDS). In one embodiment, VDS represents the voltage potential set up between the drain region 204 and the source region 202 . In FIG. 2C, the curve plotted as 205 represents the conduction behavior of a conventional transistor where the transistor is not programmed (is normal or not stressed) according to the teachings of the present invention. The curve 207 represents the conduction behavior of the programmed transistor (stressed), described above in connection with FIG. 2A, according to the teachings of the present invention. As shown in FIG. 2C, for a particular drain voltage, VDS, the current signal (IDS 2 ) detected at the second source/drain region 204 for the programmed transistor (curve 207 ) is significantly lower than the current signal (IDS 1 ) detected at the second source/drain region 204 for the conventional transistor cell (curve 205 ) which is not programmed according to the teachings of the present invention. Again, this is attributed to the fact that the channel 206 in the programmed transistor of the present invention has a different voltage threshold.
Some of these effects have recently been described for use in a different device structure, called an NROM, for flash memories. This latter work in Israel and Germany is based on employing charge trapping in a silicon nitride layer in a non-conventional flash memory device structure. Charge trapping in silicon nitride gate insulators was the basic mechanism used in MNOS memory devices, charge trapping in aluminum oxide gates was the mechanism used in MIOS memory devices, and one of the present inventors, along with another, has previously disclosed charge trapping at isolated point defects in gate insulators. However, none of the above described references addressed forming transistor cells utilizing charge trapping in potential wells in oxide insulator nanolaminate layers formed by the different electron affinities of the insulators.
FIG. 3 illustrates an embodiment for a portion of a memory array 300 according to the teachings of the present invention. The memory in FIG. 3, is shown illustrating a number of vertical pillars, or transistor cells, 301 - 1 , 301 - 2 , . . . , 301 -N, formed according to the teachings of the present invention. As one of ordinary skill in the art will appreciate upon reading this disclosure, the number of vertical pillar are formed in rows and columns extending outwardly from a substrate 303 . As shown in FIG. 3, the number of vertical pillars, 301 - 1 , 301 - 2 , . . . , 301 -N, are separated by a number of trenches 340 . According to the teachings of the present invention, the number of vertical pillars, 301 - 1 , 301 - 2 , . . . , 301 -N, serve as transistors including a first source/drain region, e.g. 302 - 1 and 302 - 2 respectively. The first source/drain region, 302 - 1 and 302 - 2 , is coupled to a sourceline 304 . As shown in FIG. 3, the sourceline 304 is formed in a bottom of the trenches 340 between rows of the vertical pillars, 301 - 1 , 301 - 2 , . . . , 301 -N. According to the teachings of the present invention, the sourceline 304 is formed from a doped region implanted in the bottom of the trenches 340 . A second source/drain region, e.g. 306 - 1 and 306 - 2 respectively, is coupled to a bitline (not shown). A channel region 305 is located between the first and the second source/drain regions.
As shown in FIG. 3, oxide insulator nanolaminate layers, shown generally as 309 , are separated from the channel region 305 by a first oxide layer 307 in the trenches 340 along rows of the vertical pillars, 301 - 1 , 301 - 2 , . . . , 301 -N. In the embodiment shown in FIG. 3, a wordline 313 is formed across the number of pillars and in the trenches 340 between the oxide insulator nanolaminate layers 309 . The wordline 313 is separated from the pillars and the oxide insulator nanolaminate layers 309 by a second oxide layer 317 .
FIG. 4 illustrates an electrical equivalent circuit 400 for the portion of the memory array shown in FIG. 3. As shown in FIG. 4, a number of vertical transistor cells, 401 - 1 , 401 - 2 , . . . , 401 -N, are provided. Each vertical transistor cell, 401 - 1 , 401 - 2 , . . . , 401 -N, includes a first source/drain region, e.g. 402 - 1 and 402 - 2 , a second source/drain region, e.g. 406 - 1 and 406 - 2 , a channel region 405 between the first and the second source/drain regions, and oxide insulator nanolaminate layers, shown generally as 409 , separated from the channel region by a first oxide layer.
FIG. 4 further illustrates a number of bit lines, e.g. 411 - 1 and 411 - 2 . According to the teachings of the present invention as shown in the embodiment of FIG. 4, a single bit line, e.g. 411 - 1 is coupled to the second source/drain regions, e.g. 406 - 1 and 406 - 2 , for a pair of transistor cells 401 - 1 and 401 - 2 since, as shown in FIG. 3, each pillar contains two transistor cells. As shown in FIG. 4, the number of bit lines, 411 - 1 and 411 - 2 , are coupled to the second source/drain regions, e.g. 406 - 1 and 406 - 2 , along rows of the memory array. A number of word lines, such as wordline 413 in FIG. 4, are coupled