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[0001] 1. Field of the Invention
[0002] The present invention relates to a light emitting device used in a back light of a liquid crystal display, a panel meter, an indicator light, a surface emitting optical switch, or the like. The present invention also relates to a light receiver device used in an optical receiver for an optical sensor, or the like, as well as the optical devices using the light emitting device or light receiving device.
[0003] 2. Discussion of the Related Art
[0004] A semiconductor element can be used as a light emitting element or a light receiving element. Also, a semiconductor device can include a support part protecting the light emitting element and/or the light receiving element from the external environment, and lead electrodes connecting them.
[0005] When used as a light emitting device, a light emitting diode is capable of emitting mixed light in a white range with a high intensity by a combination of light from a light emitting element and a phosphor which absorbs the light and emits light in a different wavelength. A light source comprising light emitting diodes set in an array has been used in various areas. In such a light emitting diode, the light emitting elements can be fixed to a support member called a package so as to comprise the light emitting device. For example, a surface-mounted light emitting device has a light emitting surface of the light emitting device facing perpendicular to the mounting surface of the light emitting device. This device is capable of emitting light approximately parallel to the surface of the package as is disclosed in Japanese Unexamined Patent Publication No. 2000-196153.
[0006] Also, a light source is known where light from a light emitting diode is introduced to a translucent member through a light entrance face. The light emitting diode is fixed to the light entrance face. The light is then guided through the translucent member and is extracted from an output surface of the translucent member. These light sources include a planar light source such as a backlight for a liquid crystal display.
[0007] The outer shape of the package comprises thin film electrodes on an insulated base material. The insulated base material greatly contracts under high temperature and it has been hard to maintain uniform shapes for the base material. Furthermore, since this type of package uses thin film electrodes, the heat release rate goes down as the package is downsized. Consequently, the package includes a molded body formed by resin injection molding to try to make the light emitting device thinner and smaller, and to improve the rate of heat released from the device. Such a package is made by injection molding so that the lead electrodes can be inserted in the package.
[0008] After forming the package, portions of the lead electrodes which protrude from the side faces of the package are bent so as to facilitate the mounting of the package to the mounting base.
[0009] The lead electrodes where the semiconductor element is placed can be made with ease and can be made relatively large compared with the size of the package. This improves the heat transfer of the semiconductor element. However, when a package is formed by injection molding, a tolerance is created when bending (forming) and this results in difficulty in obtaining uniform shapes in quantity. Accordingly, when accuracy is required to mount a plurality of light emitting devices to an external support member or an optical member, it has been necessary to provide a different outer shape for each external support member or optical member, so as to fit to different shaped packages.
[0010] Consequently, the present invention has been devised to solve the above-mentioned problems. Therefore, an object of present invention is to provide a semiconductor device and an optical device using the semiconductor device having an excellent mounting efficiency using mass production.
[0011] A semiconductor device according to this invention has a semiconductor element and a support member having a recess for housing the semiconductor element. The main surfaces of tip portions of the lead electrodes are exposed in the bottom surface of the recess. The main surface of the support member has at least a first main surface and a second main surface which are respectively disposed away from the recess. According to such a configuration, the semiconductor device has a positioning shape on its main surface side, enabling the device to fit with other optical members or external support parts with high reliability and high precision positioning.
[0012] Also, the second main surface of the support member preferably has a recess and/or a protrusion. With this structure, an adhesive is used for mounting other members on the light emitting side. The adhesive can be applied to the second main surface to prevent the adhesive from flowing into the recess housing the semiconductor element. A firm attachment can be achieved with this structure without affecting the optical properties of the device.
[0013] The shapes of the recess and the protrusion on the second main surface are preferably formed by an external wall circling a depression. This wall prevents the adhesive from flowing out and allows the light emitting device to be made so as not to bond with other members or elements of the support member.
[0014] The first main surface is preferably shaped to have notch enabling more accurate placement of the device. Another member which has a shape that is capable of fitting into the notch allows this accurate relative placement.
[0015] The semiconductor element may be a light emitting element having a phosphor which includes Al and at least one element selected from Y, Lu, Sc, La, Gd, Tb, Eu, Ga, In, and Sm, and activated with at least one element selected from the rare earth elements. According to such a configuration, a mixed color light can be obtained by combining light emitted from the light emitting element and the wavelength converted light emitted from the phosphor.
[0016] Additionally, the semiconductor element may be a light emitting element comprising a phosphor which includes N, at least one element selected from Be, Mg, Ca, Sr, Ba, and Zn, and at least one element selected from C, Si, Ge, Sn, Ti, Zr, and Hf, and activated with at least one element selected from the rare earth elements. According to such a configuration, a mixed color light can be obtained by combining light emitted from the light emitting element and the wavelength converted light emitted from the phosphor. Also, the color rendering properties of the mixed color light can be improved.
[0017] In the present invention, the semiconductor element may be a light emitting element. The semiconductor device can be provided with a light emitting element comprising a semiconductor of a laminated structure. This structure has an active layer of a nitride semiconductor disposed between an N-type contact layer of a nitride semiconductor having an N-side electrode, and a P-type contact layer of the nitride semiconductor having a P-side electrode. The N-type contact layer comprises a first region having a semiconductor laminated structure with a P-side electrode, and a second region which is different from the first region, on the electrode forming side. The second region has a plurality of protrusions wherein the top portions of the protrusions are arranged closer to the P-type contact layer than the active layer, when viewed in a cross sectional view of the light emitting element.
[0018] A thinner light emitting device can be obtained by arranging the longitudinal direction of the light emitting element parallel to the longitudinal direction of the bottom face of the recess of the package. Furthermore, the light extraction efficiency can also be improved, and thus, a light emitting device with high reliability can be achieved. In addition, it is more preferable that the protrusion reduces in size from the N-type contact layer toward the P-type contact layer when viewed in the cross sectional view.
[0019] According to the present invention, the optical device includes the semiconductor device and a translucent member guiding light from the semiconductor device or guiding light to the semiconductor device. The translucent member comprises a light entrance portion fitting into the main surface of the semiconductor device.
[0020] With this configuration, a plurality of light emitting devices can be mounted to a translucent member with greater accuracy and in a manner that prevents light from leaking at the intersection of the light emitting device and the translucent member. Therefore, it is possible to mass produce a planar light source with excellent reliability and excellent optical properties.
[0021] The above and other objects and features of the present invention will be clearly understood from the following description with respect to the preferred embodiments thereof when considered in conjunction with the accompanying drawings and diagrams, in which:
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[0048] After performing various tests, the inventor discovered a way for an improved mounting for a semiconductor device using an insert-type package. The package includes a portion having thermal distortion-resistant characteristics to enable the package to be positioned relative to other members. That is, in the present invention, the support part has at least a first main surface disposed adjacent to the recess for housing the semiconductor element and a second main surface disposed adjacent to and offset from the first surface. The presence of at least two main surfaces enables the positioning of the package with respect to the other members.
[0049] The present invention will be described with reference to the accompanying drawings in which preferred embodiments of the invention are shown by way of example, especially by using the example of a light emitting device. FIGS.
[0050] The light emitting device of the present invention has several embodiments. For example, as shown in
[0051] Here, the term “main surface” in the present specification refers to a surface of the light emitting device which is on the same side as the side which emits light from the light emitting element. Furthermore, the configuration of the light emitting surface formed on the main surface of the light emitting device is not limited to a rectangular shape as shown in
[0052] The positive electrode and the negative electrode of a light emitting device of the present invention are inserted so that they protrude from the side ends of the package. The protruding parts of the lead electrodes are bent rearwardly away from the main surface of the package, or they are bent toward the mounting surface perpendicular to the main surface. Here, the mounting surface is the surface that is perpendicular to the main surface of the package and that is parallel to the longer side of the recess. In this arrangement, the light emitting device of the present invention is a side light emitting type which emits light approximately parallel to the mounting surface.
[0053] The package
[0054] Attaching an optical member such as a lens having a specific shape to the device, or assembling a surface emitting light source by combining the light emitting device of present invention with an optical guide plate can be facilitated and enhances the light intensity and obtains the desired optical properties for the light emitting device in accordance with the present invention. At this time, by providing a shape on the optical member which is capable of fitting or matching with the shape of the main surface side having at least the first main surface
[0055] In addition, although the main surface has a step between the first main surface
[0056] According to the embodiment shown in
[0057] The protrusions
[0058] Additionally, as shown in
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[0060] Furthermore the recess and the protrusion may be shaped as a circular groove as shown in FIGS.
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[0064] As seen in the embodiments described above, the configuration defined by the first main surface and the second main surface of the present invention can be designed considering the position of the semiconductor, the viscosity of the adhesive as well as other factors.
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[0066] As described above, the package
[0067] However, when detaching the package, the molding member of the package still remains hot and is susceptible to deformation by external forces. For example, in the case wherein a main surface of the lead electrode
[0068] In the case where the light emitting device is downsized, the end part of the package must be arranged as the pin-knock surface. However, it is possible that the package
[0069] In contrast, the light emitting device according to the present invention has the first main surface
[0070] The configuration of the second main surface
[0071] The package
[0072] In the light emitting device according to this embodiment of the present invention, the light emitting element
[0073] In the following description, the production process and the individual components of the embodiments of the present invention will be described in more detail.
[0074] Process 1: Formation of the Lead Electrodes
[0075] In the present embodiment, the first process includes pulling a metal sheet to form a lead frame having plurality of pairs of positive and negative lead electrodes. Next, a plating operation is performed on the surface of the lead frame. In addition, a hanger lead which supports the packages throughout the production processes, from the step of lead electrode formation through the step of light emitting device partition, can be provided on a portion of the lead frame.
[0076] Lead Electrodes
[0077] The lead electrodes
[0078] Although the materials for the lead electrodes
[0079] In each portion of the pressed metal long sheet corresponding to a part of the package, an end face of the positive electrode is disposed so as to be separated from the negative electrode and opposite from an end face of the negative electrode. In the present embodiment, a specific process is not carried out on the lead electrode
[0080] Process 2: Formation of the Package
[0081] In the present embodiment, a package
[0082] Next, the metal long sheet described above is placed between the mold
[0083] Furthermore, in the case where a hanger lead is provided on the lead frame, as shown in
[0084] Molding Material
[0085] The molding material for the package used in the present invention is not specifically limited. A liquid crystal polymer, a polyphthalamide resin, a polybutylene terephthalate (PBT), or the like, as well as any other known thermoplastic resins can be used. When a semi-crystalline polymer resin containing crystals of high-melting point is used such as polyphthalamide resin, a package having a large surface energy and good adhesion with a sealing resin in the recess or with an optical guide plate, can be obtained. Accordingly, interfacial separation between the package recess and the sealing resin can be prevented when they are cooled. In addition, a white pigment substance such as titanium oxide or the like, can be mixed into the molding member of a package to enhance the efficiency of the reflection of light emitted from the light emitting chip.
[0086] The molding member formed in such a manner is detached from the mold as follows. First, the mold is opened, and the pin provided in the mold having a protrusion is thrust toward the second main surface of the package. At this moment, a cylindrical wall having an inner diameter which is the same as the size of a pinhead is formed. Such a cylindrical wall can prevent the flow of adhesive material while fixing the light emitting device to other members by using an adhesive material or the like, and can achieve an enhanced adhesive force.
[0087] Process 3: Mounting of the Semiconductor Element
[0088] Next, the semiconductor element is fixed to the lead electrode
[0089] Light Emitting Element
[0090] As an example of the semiconductor element in the present invention, a semiconductor element may be used such as a light emitting element, a light receiving element, or the like. The semiconductor element in the present embodiment can also be an LED chip used as a light emitting element.
[0091] The light emitting element
[0092] As an example of the structure of the semiconductor, a homostructure, a heterostructure or a double heterostructure having an MIS junction, a PIN junction or a P-N junction can be used. A variety of emission light wavelengths can be selected depending on the materials or the degree of the mixed crystal in the semiconductor layers. In addition, the active layer can be of a single well structure or a multiple well structure, formed as a thin film wherein a quantum effect occurs.
[0093] In the case where a nitride semiconductor is used, a material such as sapphire, spinel, SiC, Si, ZnO, GaN, or the like, is preferably used as the semiconductor substrate. It is preferable to use a sapphire substrate in order to form a nitride semiconductor having good crystallinity and which can be efficiently produced in quantity. A nitride semiconductor can be formed on the sapphire substrate in accordance with MOCVD or the like. For example, a buffer layer, such as of GaN, AlN, GaAlN, or the like, can be formed on a sapphire substrate, and a nitride semiconductor having a P-N junction can be formed thereon. Furthermore, the substrate can be removed after formation of the semiconductor layers.
[0094] An example of a light emitting element having a P-N junction using a nitride semiconductor includes, for example, a double heterostructure wherein a first contact layer of N-type gallium nitride, a first cladding layer of N-type aluminum gallium nitride, an active layer of indium gallium nitride, a second cladding layer of P-type aluminum gallium nitride, and a second contact layer of P-type gallium nitride, are layered on the buffer layer in sequence. Nitride semiconductors show N-type conductivity when in the condition where no impurities have been doped. In order to form an N-type nitride semiconductor having the desired properties such as improved light emission efficiency, it is preferable to arbitrarily introduce an N-type dopant such as Si, Ge, Se, Te, C, or the like. On the other hand, in order to form a P-type nitride semiconductor, it is preferable to dope with a P-type dopant such as Zn, Mg, Be, Ca, Sr, Ba, or the like.
[0095] Due to the fact that a nitride semiconductor is not easily converted to the P-type solely by doping a P-type dopant, it is preferable to treat such a semiconductor after introduction of the dopant in processes such as heating in a furnace or irradiation with plasma. After forming the electrodes, the semiconductor wafer is cut into chips so that the light emitting elements of the nitride semiconductor can be obtained. In addition, an insulating protective film made of materials such as SiO
[0096] In order to emit white light by using the light emitting diode of the present invention, it is preferable for the wavelength of light emitted from the light emitting element to be greater than or equal to 400 nm and less than or equal to 530 nm, and more preferably greater than or equal to 420 nm and less than or equal to 490 nm. These ranges take into consideration the complementary color relationship with fluorescent material and deterioration of the translucent resin, or the like. Furthermore, it is more preferable for the wavelength to be greater than or equal to
[0097] Bump
[0098] The light emitting element
[0099] As an example of a different bump forming process, a stud bump can be obtained by cutting the wire so as to leave the edge portion of the wire after bonding an edge portion of the conductive wire. In another process, a bump can be obtained by metal deposition after forming the desired mask pattern, or the like. In addition, a bump can be provided first to the electrode side of the light emitting element, or it can be provided to both the lead electrode side and the light emitting element side, respectively.
[0100] In addition, it is preferable to mount through a sub-mount when mounting by the flip tip method.
[0101] A conductive pattern provided by a conductive member
[0102] In order to improve the reliability of the light emitting device, an underfill can be used between the positive and negative electrode of the light emitting element and the sub-mount. An underfill can also be used in the gap existing between the positive and negative electrodes of the light emitting element and the lead electrodes
[0103] A thermosetting resin such as an epoxy resin may be used as a material for the underfill. In order to reduce thermal stress in the underfill, aluminum nitride, aluminum oxide, and their composite mixtures can be mixed into the epoxy resin. The amount of underfill required is an amount sufficient to fill the gap that occurs between the positive and negative electrodes of the light emitting element and the sub-mount.
[0104] The connection between the conductive pattern formed on the sub-mount and the electrode of the light emitting element
[0105] Conductive wires
[0106] After using die bonding to fix the light emitting element
[0107] For the conductive wires
[0108] The conductive wire is susceptible to separation at the interface of the coating portion, which includes the fluorescent material, and the molding member, which does not include the fluorescent material. Even when the same material is used for both the coating portion and the molding portion, the fluorescent material is believed to be the cause of the separation due to a difference in thermal expansion. For this reason, the diameter of the conductive wire is preferably greater than or equal to 25 μm. For the reasons of enlarging the light emitting area and ease of handling, the diameter of the conductive wire is preferably less than or equal to 35 μm. The conductive wire can be a wire made of a metal such as gold, copper, platinum, aluminum, or the like, or an alloy using these metals.
[0109] Process 4: Sealing
[0110] Next, a sealing member
[0111] Sealing member
[0112] The properties material of the sealing member
[0113] Furthermore, the sealing member can obtain a lens property by making the emission face side of the sealing member into a desired form. The sealing member
[0114] Fluorescent material
[0115] In the present invention where a semiconductor element is used as the light emitting element, a variety of fluorescent materials made of inorganic materials or organic materials can be employed. These materials can be used in or around each of the components, such as the light emitting element, the sealing member, the die bonding member, the underfilling, or the package. For example, the fluorescent material can include a rare earth element which is an inorganic fluorescent material.
[0116] For the fluorescent material having a rare earth element, a garnet type fluorescent material including at least one element selected from the group comprising Y, Lu, Sc, La, Gd, Tb and Sm, and at least one element selected from the group comprising Al, Ga and In can be used. Specifically, the aluminum-garnet phosphor used in the present embodiment can be a phosphor that contains Al and at least one element selected from Y, Lu, Sc, La, Gd, Tb, Eu, Ga, In, and Sm, and that is activated with at least one element selected from the rare earth elements. The phosphor is excited by the visible light or ultraviolet rays emitted from the light emitting element and therefore the phosphor emits light. For example, in addition to the yttrium-aluminum oxide phosphor (YAG phosphor) described below, Tb
[0117] In addition, the nitride phosphor used in the present invention is a phosphor that contains N, at least one element selected from Be, Mg, Ca, Sr, Ba and Zn, and at least one element selected from C, Si, Ge, Sn, Ti, Zr and Hf, and activated with at least one element selected from the rare earth elements. Furthermore, the nitride phosphor used in the present embodiment is a phosphor that absorbs visible light or ultraviolet rays emitted from the light emitting element or YAG phosphor and this causes a light emission from the phosphor. Examples of nitride phosphors, include (Sr
[0118] Each of the phosphors will be described in detail below.
[0119] Yttrium-Aluminum Oxide Phosphor
[0120] The fluorescent material used for the light emitting device in the present embodiment uses a yttrium aluminum oxide phosphor activated with cerium which is excited by the light emitted from the semiconductor light emitting element having an active layer, and which is capable of emitting light in different wavelengths. Specifically, YAlO
[0121] In further detail, the fluorescent material is a photoluminescence fluorescent material represented by the general formula (Y
[0122] The excitation luminous efficiency in the long-wavelength range of 460 nm and above can be improved by including Gd in the crystal of the photoluminescence fluorescent material. By increasing in the content of Gd, the peak emission wavelength shifts toward a longer wavelength, and the wavelength of the entire emission spectrum also shifts toward longer wavelengths. That is, when emission of a more reddish light is required, it can be obtained by increasing the degree of substitution of Gd. On the other hand, when the Gd content is increased, the light of photoluminescence in terms of blue light tends to decrease. Tb, Cu, Ag, Au, Fe, Cr, Nd, Dy, Co, Ni, Ti, Eu, Pr, or the like can be included in addition to Ce if desired.
[0123] In addition, by substituting a part of Al with Ga in the composition of yttrium aluminum garnet fluorescent material, the emission wavelength can be shifted toward a shorter wavelength. On the other hand, by substituting a part of Y with Gd, the emission wavelength can be shifted toward a longer wavelength. When substituting a part of Y with Gd, it is preferable to limit the substituted Gd to less than 10%, while adjusting the degree of substitution of Ce from 0.03 to 1.0 in the molar ratio. When substituted Gd content is less than 20%, the green component in the emission is greater and that of the red component is less. However, by increasing the content of Ce, the red component in the emission can be compensated, and a desired color tone can be obtained without decreasing the luminance. According to such a configuration, desirable temperature characteristics of the fluorescent material can be obtained, thereby improving the reliability of the light emitting diode. Also, when the photoluminescence fluorescent material that is adjusted to include a more reddish component is used, a compound color such as pink can be emitted, thereby enabling the light emitting device to be formed with excellent color rendering properties.
[0124] The raw material for making such a photoluminescence fluorescent material is made in such a way that sufficiently mixes oxides of Y, Ga, Gd, Al, and Ce or compounds which can be easily converted into these oxides at high temperature as raw materials for Y, Ga, Gd, Al, and Ce in accordance with the stoichiometric ratio. The mixture material may also be made by dissolving rare earth elements Y, Gd, and Ce in stoichiometric proportions in an acid, coprecipitating the solution with oxalic acid and firing the coprecipitation to obtain an oxide of the coprecipitate, and then mixing it with aluminum oxide.
[0125] The obtained raw material is mixed with an appropriate amount of fluoride, such as barium fluoride or ammonium fluoride used as a flux, and is charged into a crucible and fired at 1350-1450° C. in air for 2 to 5 hours to obtain the calcinated material. The calcinated material is then ball-milled in water, washed, separated, dried, and finally, sieved thereby obtaining the desired material.
[0126] Also, the firing above is preferably carried out in two steps. The first step includes firing the mixture of raw materials for the fluorescent material and the flux in air or in a slightly reduced atmosphere. The second step includes firing them in a reduced atmosphere. The slightly reduced atmosphere means an atmosphere containing at least the necessary amount of oxygen for the reaction process to form a desired fluorescent material from the mixed raw materials. By carrying out the first firing step in the slightly reduced atmosphere until the formation of the desired structure for the fluorescent material has completed, darkening of the fluorescent material and deterioration in its light absorbing efficiency can be prevented.
[0127] Also, the reduced atmosphere in the second firing step means an reduced atmosphere stronger in the degree of reduction than the above discussed slightly reduced atmosphere. Therefore, a light emitting device employing a fluorescent material produced as described above can achieve a reduction in the quantity of phosphor necessary to obtain light with a desired color tone. It is also possible to obtain a light emitting device having an excellent light extraction efficiency.
[0128] Silicon Nitride Fluorescent Material
[0129] Also, a fluorescent material which is excited by absorbing light such as visible light emitted from the light emitting element, ultraviolet or light emitted from other fluorescent materials to thereby emit light, can be used. Specifically, a silicon nitride fluorescent material in which Mn is added, such as Sr—Ca—Si—N:Eu, Ca—Si—N:Eu, Sr—Si—N:Eu, Sr—Ca—Si—O—N:Eu, Ca—SiO—N:Eu, and Sr—Si—O—N:Eu, as component elements can be used. The fluorescent materials described above are represented by general formulas L
[0130] More specifically, it is preferable to use a fluorescent material in which Mn is added and represented by the general formulas (Sr
[0131] When Eu
[0132] Also, by including at least one element selected from the group consisting of Mg, Sr, Ca, Ba, Zn, B, Al, Cu, Mn, Cr, O, and Ni, a fluorescent material can easily be obtained in a large particle size with an improved luminance. Also, B, Al, Mg, Cr, and Ni have properties that can restrain afterglow.
[0133] The nitride fluorescent material described above absorbs a portion of blue light and emits light from the yellow region to the red region. A combination of such a nitride fluorescent material with a fluorescent material which emits yellow light such as a YAG fluorescent material, and a light emitting element which emits blue light, enables a light emitting device to emit white light with a warm tone by mixing light in the yellow to red light region with the blue light. The light emitting device emitting mixed light in the white region can increase the special color rendering index R9 close to 40 at the color temperature of about Tcp=4600 K.
[0134] Next, the production method of the fluorescent material according to the present invention ((Sr
[0135] The raw materials of Sr and Ca are ground. It is preferable to use elemental Sr and Ca for the raw materials, however, a compound such as an imide or an amide can be used. Also, B, Al, Cu, Mn, Al
[0136] The Si raw material is ground. It is preferable to use elemental Si, however, a nitride, an imide, an amide, or the like, can also be used. For example, Si
[0137] Next, nitride compounds of Sr and Ca can be formed in a nitrogen atmosphere. The reaction formulas are shown by the following formulas, respectively.
[0138] Forming a nitride of Sr and Ca is carried out in a nitrogen atmosphere at from 600° C. to 900° C. for about 5 hours. Nitrides of Sr and Ca can be formed either as a mixture or individually. The nitrides of Sr and Ca are preferably of a high purity, however, a commercially available material can also be used.
[0139] Next, forming a nitride of Si raw material is carried out in a nitrogen atmosphere. The reaction formula is shown below in formula 3.
[0140] A nitride of Si can be made in a nitrogen atmosphere at 800° C. to 1200° C. for about 5 hours. The silicon nitride used in the present invention is preferably of a high purity, however, a commercially available material can also be used.
[0141] Grinding is carried out on the nitride of Sr, Ca, or Sr—Ca. Sr, Ca, or a nitride of Sr—Ca is ground in an argon or nitrogen atmosphere in a glove box.
[0142] Similarly, grinding is carried out for the nitride of Si. Also, an Eu compound, Eu
[0143] The raw materials described above can include at least one element selected from the group consisting of Mg, Sr, Ca, Ba, Zn, B, Al, Cu, Mn, Cr, O, and Ni. Also, the above elements, such as Mg, Zn, and B, may be mixed in the mixing process described below, in a predetermined compounding ratio. The elements described above can also be added to the raw materials individually, however, they are usually added as a compound. Compounds of this kind include H
[0144] After grinding, Sr, Ca, a nitride of Sr—Ca, silicon nitride, Eu
[0145] Finally, the mixture of Sr, Ca, a nitride of Sr—Ca, silicon nitride, Eu
[0146] A tubular furnace, a compact furnace, a high-frequency furnace, a metal furnace, or the like, can be used for firing. The firing can be carried out in the temperature range of from 1200° C. to 1700° C, however, the range from 1400° C. to 1700° C. is more preferable.
[0147] As for firing, a one step firing method in which the furnace temperature is gradually increased, and the firing is carried out at 1200° C. to 1500° C. for several hours, is preferable. However, a two step firing method (the multistage firing) wherein the first firing step is carried out at 800° C. to 1000° C., and the furnace temperature is gradually increased, and the second firing step is carried out at 1200° C. to 1500° C., can also be employed. The raw material of the fluorescent material is preferably fired using a crucible or a boat made of boron nitride (BN). Other than a crucible of boron nitride material, an alumina (Al
[0148] Using the above production process, the desired fluorescent material can be obtained.
[0149] In addition, the fluorescent material that is capable of emitting a reddish light and that is usable in the present embodiment is not particularly limited and can include, for example, Y
[0150] The phosphors capable of emitting a reddish light are typified by aluminum garnet phosphors and nitride phosphors, produced as described above. These phosphors can be included in the single phosphor layer where more than two kinds of phosphors are included, or they can be included in the two layers of phosphor where each layer includes one or more than one kind of phosphor, formed around the light emitting element. The phosphor layer is formed by means of potting or stencil plate printing using an inorganic translucent member, such as a translucent resin or glass as adhesives.
[0151] Also, it is possible to use a method where the phosphor layer is formed after fixing the semiconductor light emitting element to the support member. It is also possible to use a method where the phosphor layer is formed on the semiconductor wafer, and is subsequently cut into chips. It is also possible to use a combination of both of these methods. According to such a configuration, a mixed light made up of light emitted from different kinds of phosphors can be obtained. In order to improve the mixing of light emitted from each fluorescent material and to decrease unevenness of the light, it is preferable that each kind of phosphor has a similar average diameter and shape. Also, it is preferable to arrange the nitride phosphor so it is placed closer to the light emitting element than the YAG phosphor. This is done because of consideration of the nitride phosphor absorbing a portion of light that is a converted wavelength from the YAG phosphor. According to such a configuration, absorption of a portion of the wavelength-converted light of the YAG phosphor by the nitride phosphor can be eliminated. Thus, the color rendering property of the mixed light can be improved compared to the case in which a mixture of a YAG phosphor and a nitride phosphor is included.
[0152] Alkaline Earth Metal Halogen Apatite Fluorescent Material An alkaline earth metal halogen apatite fluorescent material activated with Eu, including at least one element represented by M and selected from Mg, Ca, Ba, Sr, and Zn, and at least one element represented by M′ and selected from Mn, Fe, Cr, and Sn, can also be used. This composition enables the production of a light emitting device capable of emitting white light of a high luminance with good mass productivity. Especially, an alkaline earth metal halogen apatite fluorescent material activated with Eu and including at least one of Mn and Cl, has excellent light properties and weatherability. In addition, the fluorescent material can efficiently absorb light in the emission spectrum emitted from the nitride semiconductor. Furthermore, the fluorescent material is capable of emitting a white light, and can adjust the region of the white light range according to its composition. Additionally, the fluorescent material absorbs the ultraviolet rays and emits a yellow or red light having a high intensity. In addition, an example of an alkaline earth metal halogen apatite fluorescent material such as an alkaline earth metal chlorapatite fluorescent material can be included.
[0153] In the case of an alkaline earth metal halogen apatite fluorescent material represented by the general formula (M
[0154] Furthermore, in addition to the alkaline earth metal halogen apatite fluorescent material, in the case when at least one kind of fluorescent material selected from BaMg
[0155] Also, the particle diameter of the fluorescent material used in the present invention is preferably in the range of from 1 μm to 100 μm, and more preferably in the range of 15 μm to 30 μm. A fluorescent material having the particle diameter of less than 15 μm tends to form an aggregation, and is densely settled down in a liquid resin, thereby decreasing the transmission efficiency of the light.
[0156] In the present invention, such an obstruction of light by the fluorescent material is prevented by employing a fluorescent material that does not have this tendency and thereby this improves the output of the light emitting element. Furthermore, a fluorescent material having a particle diameter in the range of the present invention has excellent properties for light absorption and light conversion efficiency, and has a broad excitation wavelength. Thus, by including a fluorescent material with a large particle diameter having excellent optical properties, it is also possible to efficiently convert wavelengths near the peak wavelength of light emitted from the light emitting element.
[0157] Here, the particle size in the present invention indicates the value obtained from the mass base particle size distribution. The mass base particle size distribution is obtained by measuring the particle distribution by means of a laser diffraction scattering method. Specifically, when the ambient temperature is 25° C. and the moisture content is 70%, each material is dispersed in a hexametaphosphoric acid having a concentration of 30%. The particle size distribution is then measured with a laser diffraction scattering-type device (SALD-2000A, Shimadzu Corp.) in a particle size range from 0.03 μm to 700 μm. The median diameter in the present specification indicates the particle size at the cumulative size distribution value of 50% in the mass base particle size distribution. The median diameter of the fluorescent material used in the present invention is preferably from 15 μm to 50 μm. Also, it is preferable to include a fluorescent material having a median diameter with the abovementioned range with a high frequency rate, preferably from 20% to 50%. By using such a fluorescent material having a small degree of fluctuation in particle diameter as just described, lack of uniformity in the distribution of the light color can be prevented, and a light emitting device capable of emitting favorable color tones of light can be obtained.
[0158] Also, it is preferable for the fluorescent material to have a shape similar to that of a dispersing agent used in the present invention. The term similar shape as used in the present specification means the difference in the deviation from circular (deviation from circular=circumference of a circle having equal area to the projected area of a particle/peripheral length of projection of a particle) among the particles is less than 20%. The deviation from circular indicates the degree of approximation away from a perfect circle. Accordingly, the light diffused by a dispersing agent and the light emitted from the excited fluorescent material are mixed in an ideal state, thereby a more uniform emission can be achieved.
[0159] Process 5: Separation Into Each Light Emitting Device
[0160] Next, each connecting part of the lead frame to each electrode is cut to form separate individual light emitting devices. Furthermore, where the package
[0161] Process 6: Forming the Lead Electrode
[0162] Next, the positive and negative electrodes protruding from the end face of the package
[0163] In the case where the positive lead electrode and the negative electrode protrude from the end faces of the minor axis sides of the main surface of the package in the present embodiment, it is preferable to bend the protruding portion toward the back side of the package, opposite from the main surface (see for example,
[0164] Also, by bending the protruding portion of the lead electrodes, the light emitting device can be prevented from being pushed up from a temporary mounting face at the time when the reflow process is carried out such that the light emitting device is temporarily mounted to the mounting base. When the connection terminal portions are formed by bending the lead frames in this way, it is preferable that the wall face of the molding member on the mounting face side and the exposed faces of the lead electrodes are arranged so as to be on approximately the same plane. According to this configuration, the light emitting device can be mounted stably on the mounting base member.
[0165] Also, the structure of the contact terminal portion is not limited to the J-bend type and it may be made to have other structures such as a gull-wing type.
[0166] In the present embodiment, the area around the side faces where the lead electrodes are exposed, are preferably formed with a tapered shape which is tapered with predetermined angles, as shown in
[0167] The light emitting device of the present embodiment can be produced according to the above described processes.
[0168] The light emitting device thus formed is placed on the mounting base with a predetermined spacing to establish the electric conduction. It is preferable that the base member for the wiring base have excellent thermal conductivity, and an aluminum-based substrate, a ceramic-based substrate, or the like. In addition, where the surface of a substrate has a low thermal conductivity, such as a glass epoxy substrate or a paper phenol substrate, it is preferable to provide for heat release, by using a thermal pad, a thermal via, or the like. Also, electric conduction can be established between the light emitting diode and the wiring base by means of a conductive member, such as a solder. It is preferable to use a silver paste when taking the thermal release into consideration.
[0169] Translucent Member
[0170] In the present invention, a configuration capable of accurately fitting in the light entrance portion of the translucent member such as a lens or an optical guide plate made of a rigid-type translucent resin or glass or the like, can be made on the emission side or the light receiving side of the light emitting device. Here, “the light entrance-emitting portion” in the present specification is formed in the translucent member which directs light in a desired direction from the semiconductor device or directs light to the semiconductor device, and is a portion wherein the light from the semiconductor device enters. In some cases, this portion is called the “light entrance portion”. It is also a portion where the light is emitted toward the semiconductor device (in some cases, it is called the “emission portion”).
[0171] The translucent member in the present embodiment is a member where the reflection and refraction of light is used for guiding the incident light introduced in the member emitted from the light emitting device, in a predetermined direction. The translucent member also releases the light introduced into the translucent member, while adding a predetermined intensity distribution to the light. Also, the translucent member in other embodiments is a member which condenses light from the outside of the photo acceptance device which enters the translucent member in the direction of the photodetector.
[0172] Especially in the present embodiment, the translucent member used in the light emitting device has portions which individually introduce the incident light emitted from the light emitting device. The inner wall of the portion introducing the light has at least a mounting face contiguous with the first main surface, and a second mounting face contiguous with the second main surface of the light emitting device of the present mode. In addition, the portion introducing the incident light can be configured to fit the notched portion
[0173] As described above, according to the present invention, a light source having desired optical properties can be produced with a good process yield, by having the molding member capable of producing substantially constant shapes at all times, and by providing a configuration on the surface of the molding member which enables positioning with other translucent members.
[0174] Planar Light Source
[0175] The light source comprising an optical guide plate and a light emitting device may be a planar light source. In this planar light source, light enters from the light introducing portion at the side face of the optical guide plate and is released from another side face.
[0176] The optical guide plate of the present embodiment is a tabular translucent member, which uses the reflection of light on the inner wall of the member to guide the light from the light emitting device in a predetermined direction and release the light from the predetermined face to the outside of the tabular translucent member. Particularly, the optical guide plate of the present embodiment is a tabular optical guide body having a light releasing face which can be used as a planar light source for a backlight in a liquid crystal display, or the like.
[0177] As for the material for the optical guide plate, it is preferable to have excellent light permeability and good molding properties. An organic member such as an acrylic resin, a polycarbonate resin, an amorphous polyolefin resin, polystyrene resin, or the like, or an inorganic member such as glass or the like, can be used. In addition, it is preferable that the surface of the optical light guide plate have a profile irregularity of not more than 25 μm (cf. Japanese Industrial Standard).
[0178] Such an optical guide plate is installed so as to arrange the mounted face so that it sets the light introducing portion opposite to the main surface of the light emitting device. As for the installing method of the optical guide plate, a method such as fastening with a screw, adhesive bonding, welding, or the like, which is capable of easily positioning and secure bonding, can be used. The particular method can be selected according to a desired specification or requirement.
[0179] In the present embodiment, the second main surface of the package and the end face of the optical guide plate can be fastened together by an adhesive. Also, a diffusion sheet can be provided above the planar light source of the present invention. Thus, the present invention can be used as a light source for a direct type back light which illuminates other members such as a diffusion sheet or the like. The selection of the diffusion sheet has a decisive influence on the thickness and performance of the optical guide plate. Therefore, selection and evaluation of the diffusion sheet is preferably carried out in each case, according to the desired specification and requirements.
[0180] In the present embodiment, a diffusion sheet of about 100 μm in thickness, haze value of from 88% to 90% is used for a polycarbonate optical guide plate of 20 mm in thickness with excellent thermal resistance. Thus, unevenness of the light distribution between each of the light sources can be reduced and a uniform emission can be achieved. Such a diffusion sheet can be loaded on the optical guide plate directly or by means of welding. Also, when a cover lens is placed above the light source, the diffusion sheet can be fixed by placing it between the cover lens and the optical guide plate. The distance between the diffusion sheet and the optical guide plate is preferably from 0 mm to 10 mm. PET is most commonly used as the material for the diffusion sheet. However, the diffusion sheet is not limited to this material except that it should have a resistance against deforming or deteriorating due to heat generated by the light emitting diode.
[0181] The planar type light source thus obtained is capable of emitting light which is uniform and high in luminance over the entire area.
[0182] The following examples further illustrate the present invention in detail but are not to be construed to limit the scope thereof.
[0183] A surface mounting type of light emitting device is shown in